preparation of salts
This question is about testing for the presence of sulfate ions ($$\mathrm{SO}_{4}^{2-}$$) in a solution using acidified barium chloride or barium nitrate.
Explanation:
(i) Observation: When barium chloride or barium nitrate is added to a solution containing sulfate ions, a white precipitate of barium sulfate ($$\mathrm{BaSO}_{4}$$) forms.
This is because barium sulfate is insoluble in water, and its formation indicates the presence of sulfate ions.
(ii) Ionic Equation: The reaction that occurs can be represented by the ionic equation:
$$
\mathrm{Ba}^{2+}(\mathrm{aq}) + \mathrm{SO}_{4}^{2-}(\mathrm{aq}) \rightarrow \mathrm{BaSO}_{4}(\mathrm{s})
$$
This equation shows that barium ions ($$\mathrm{Ba}^{2+}$$) from the barium chloride or barium nitrate react with sulfate ions ($$\mathrm{SO}_{4}^{2-}$$) to form the insoluble barium sulfate precipitate ($$\mathrm{BaSO}_{4}$$).
The state symbols indicate that barium ions and sulfate ions are in aqueous solution, while barium sulfate is a solid precipitate.